TY  - JOUR
AU  - Vijayakumar, Vidyanand
AU  - Ghosh, Meena
AU  - Asokan, Kiran
AU  - Sukumaran, Santhosh Babu
AU  - Kurungot, Sreekumar
AU  - Mindemark, Jonas
AU  - Brandell, Daniel
AU  - Winter, Martin
AU  - Nair, Jijeesh
TI  - 2D Layered Nanomaterials as Fillers in Polymer Composite Electrolytes for Lithium Batteries
JO  - Advanced energy materials
VL  - 13
IS  - 15
SN  - 1614-6832
CY  - Weinheim
PB  - Wiley-VCH
M1  - FZJ-2023-02442
SP  - 2203326
PY  - 2023
AB  - Polymer composite electrolytes (PCEs), i.e., materials combining the disciplines of polymer chemistry, inorganic chemistry, and electrochemistry, have received tremendous attention within academia and industry for lithium-based battery applications. While PCEs often comprise 3D micro- or nanoparticles, this review thoroughly summarizes the prospects of 2D layered inorganic, organic, and hybrid nanomaterials as active (ion conductive) or passive (nonion conductive) fillers in PCEs. The synthetic inorganic nanofillers covered here include graphene oxide, boron nitride, transition metal chalcogenides, phosphorene, and MXenes. Furthermore, the use of naturally occurring 2D layered clay minerals, such as layered double hydroxides and silicates, in PCEs is also thoroughly detailed considering their impact on battery cell performance. Despite the dominance of 2D layered inorganic materials, their organic and hybrid counterparts, such as 2D covalent organic frameworks and 2D metal–organic frameworks are also identified as tuneable nanofillers for use in PCE. Hence, this review gives an overview of the plethora of options available for the selective development of both the 2D layered nanofillers and resulting PCEs, which can revolutionize the field of polymer-based solid-state electrolytes and their implementation in lithium and post-lithium batteries.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000947031300001
DO  - DOI:10.1002/aenm.202203326
UR  - https://juser.fz-juelich.de/record/1008641
ER  -