Home > Publications database > Direct Visualization of Distorted Twin Boundaries in Ce-Doped GdFeO3 > print |
001 | 1009338 | ||
005 | 20240712113124.0 | ||
024 | 7 | _ | |a 10.1021/acs.nanolett.3c00318 |2 doi |
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100 | 1 | _ | |a Ran, Ke |0 P:(DE-Juel1)174238 |b 0 |e Corresponding author |
245 | _ | _ | |a Direct Visualization of Distorted Twin Boundaries in Ce-Doped GdFeO3 |
260 | _ | _ | |a Washington, DC |c 2023 |b ACS Publ. |
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520 | _ | _ | |a Utilizing advanced transmission electron microscopy (TEM), the structure at the (110)-type twin boundary (TB) of Ce-doped GdFeO3 (C-GFO) has been investigated with picometer precision. Such a TB is promising to generate local ferroelectricity within a paraelectric system, while precise knowledge about its structure is still largely missing. In this work, a direct measurement of the cation off-centering with respect to the neighboring oxygen is enabled by integrated differential phase contrast (iDPC) imaging, and up to 30 pm Gd off-centering is highly localized at the TB. Further electron energy loss spectroscopy (EELS) analysis demonstrates a slight accumulation of oxygen vacancies at the TB, a self-balanced behavior of Ce at the Gd sites, and a mixed occupation of Fe2+ and Fe3+ at the Fe sites. Our results provide an informative picture with atomic details at the TB of C-GFO, which is indispensable to further push the potential of grain boundary engineering. |
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773 | _ | _ | |a 10.1021/acs.nanolett.3c00318 |0 PERI:(DE-600)2048866-X |n 7 |p 2945-2951 |t Nano letters |v 23 |y 2023 |x 1530-6984 |
856 | 4 | _ | |u https://juser.fz-juelich.de/record/1009338/files/Direct%20Visualization.pdf |y Published on 2023-03-27. Available in OpenAccess from 2024-03-27. |
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