001     1018618
005     20240712113058.0
024 7 _ |a 10.1021/acsami.3c12797
|2 doi
024 7 _ |a 1944-8244
|2 ISSN
024 7 _ |a 1944-8252
|2 ISSN
024 7 _ |a 10.34734/FZJ-2023-04933
|2 datacite_doi
024 7 _ |a 37936378
|2 pmid
024 7 _ |a WOS:001108455000001
|2 WOS
037 _ _ |a FZJ-2023-04933
082 _ _ |a 600
100 1 _ |a Weintz, Dominik
|0 P:(DE-Juel1)190619
|b 0
|e First author
|u fzj
245 _ _ |a Tailoring the Preformed Solid Electrolyte Interphase in Lithium Metal Batteries: Impact of Fluoroethylene Carbonate
260 _ _ |a Washington, DC
|c 2023
|b Soc.
336 7 _ |a article
|2 DRIVER
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|b journal
|m journal
|0 PUB:(DE-HGF)16
|s 1705295569_12154
|2 PUB:(DE-HGF)
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a Journal Article
|0 0
|2 EndNote
520 _ _ |a The film-forming electrolyte additive/co-solvent fluoroethylene carbonate (FEC) can play a crucial role in enabling high-energy-density lithium metal batteries (LMBs). Its beneficial impact on homogeneous and compact lithium (Li) deposition morphology leads to improved Coulombic efficiency (CE) of the resulting cell chemistry during galvanostatic cycling and consequently an extended cell lifetime. Herein, the impact of this promising additive/co-solvent on selected properties of LMBs is systematically investigated by utilizing an in-house developed lithium pretreatment method. The results reveal that as long as FEC is present in the organic carbonate-based electrolyte, a dense mosaic-like lithium morphology of Li deposits with a reduced polarization of only 20 mV combined with a prolonged cycle life is achieved. When the pretreated Li electrodes with an FEC-derived preformed SEI (pSEI) are galvanostatically cycled with the FEC-free electrolyte, the described benefits induced by the additive are not observable. These results underline that the favorable properties of the FEC-derived SEI are beneficial only if there is unreacted FEC in the electrolyte formulation left to constantly reform the interphase layer, which is especially important for anodes with high-volume changes and dynamic surfaces like lithium metal and lithiated silicon.
536 _ _ |a 1221 - Fundamentals and Materials (POF4-122)
|0 G:(DE-HGF)POF4-1221
|c POF4-122
|f POF IV
|x 0
536 _ _ |a BMBF-13XP0511B - Lillint-2 Thermodynamic and kinetic stability of the Lithium-Liquid Electrolyte Interface (BMBF-13XP0511B)
|0 G:(DE-Juel1)BMBF-13XP0511B
|c BMBF-13XP0511B
|x 1
588 _ _ |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de
700 1 _ |a Kühn, Sebastian P.
|0 P:(DE-Juel1)179440
|b 1
700 1 _ |a Winter, Martin
|0 P:(DE-Juel1)166130
|b 2
|u fzj
700 1 _ |a Cekic-Laskovic, Isidora
|0 P:(DE-Juel1)171204
|b 3
|e Corresponding author
|u fzj
773 _ _ |a 10.1021/acsami.3c12797
|g Vol. 15, no. 46, p. 53526 - 53532
|0 PERI:(DE-600)2467494-1
|n 46
|p 53526 - 53532
|t ACS applied materials & interfaces
|v 15
|y 2023
|x 1944-8244
856 4 _ |y OpenAccess
|u https://juser.fz-juelich.de/record/1018618/files/weintz-et-al-2023-tailoring-the-preformed-solid-electrolyte-interphase-in-lithium-metal-batteries-impact-of.pdf
856 4 _ |y OpenAccess
|x icon
|u https://juser.fz-juelich.de/record/1018618/files/weintz-et-al-2023-tailoring-the-preformed-solid-electrolyte-interphase-in-lithium-metal-batteries-impact-of.gif?subformat=icon
856 4 _ |y OpenAccess
|x icon-1440
|u https://juser.fz-juelich.de/record/1018618/files/weintz-et-al-2023-tailoring-the-preformed-solid-electrolyte-interphase-in-lithium-metal-batteries-impact-of.jpg?subformat=icon-1440
856 4 _ |y OpenAccess
|x icon-180
|u https://juser.fz-juelich.de/record/1018618/files/weintz-et-al-2023-tailoring-the-preformed-solid-electrolyte-interphase-in-lithium-metal-batteries-impact-of.jpg?subformat=icon-180
856 4 _ |y OpenAccess
|x icon-640
|u https://juser.fz-juelich.de/record/1018618/files/weintz-et-al-2023-tailoring-the-preformed-solid-electrolyte-interphase-in-lithium-metal-batteries-impact-of.jpg?subformat=icon-640
909 C O |o oai:juser.fz-juelich.de:1018618
|p openaire
|p open_access
|p driver
|p VDB
|p openCost
|p dnbdelivery
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 0
|6 P:(DE-Juel1)190619
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 1
|6 P:(DE-Juel1)179440
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 2
|6 P:(DE-Juel1)166130
910 1 _ |a Forschungszentrum Jülich
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)171204
913 1 _ |a DE-HGF
|b Forschungsbereich Energie
|l Materialien und Technologien für die Energiewende (MTET)
|1 G:(DE-HGF)POF4-120
|0 G:(DE-HGF)POF4-122
|3 G:(DE-HGF)POF4
|2 G:(DE-HGF)POF4-100
|4 G:(DE-HGF)POF
|v Elektrochemische Energiespeicherung
|9 G:(DE-HGF)POF4-1221
|x 0
914 1 _ |y 2023
915 p c |a APC keys set
|0 PC:(DE-HGF)0000
|2 APC
915 p c |a Local Funding
|0 PC:(DE-HGF)0001
|2 APC
915 p c |a DFG OA Publikationskosten
|0 PC:(DE-HGF)0002
|2 APC
915 p c |a Helmholtz: American Chemical Society 01/01/2023
|0 PC:(DE-HGF)0122
|2 APC
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0150
|2 StatID
|b Web of Science Core Collection
|d 2023-10-25
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0300
|2 StatID
|b Medline
|d 2023-10-25
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1160
|2 StatID
|b Current Contents - Engineering, Computing and Technology
|d 2023-10-25
915 _ _ |a Creative Commons Attribution CC BY 4.0
|0 LIC:(DE-HGF)CCBY4
|2 HGFVOC
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)1150
|2 StatID
|b Current Contents - Physical, Chemical and Earth Sciences
|d 2023-10-25
915 _ _ |a IF >= 5
|0 StatID:(DE-HGF)9905
|2 StatID
|b ACS APPL MATER INTER : 2022
|d 2023-10-25
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0200
|2 StatID
|b SCOPUS
|d 2023-10-25
915 _ _ |a WoS
|0 StatID:(DE-HGF)0113
|2 StatID
|b Science Citation Index Expanded
|d 2023-10-25
915 _ _ |a OpenAccess
|0 StatID:(DE-HGF)0510
|2 StatID
915 _ _ |a JCR
|0 StatID:(DE-HGF)0100
|2 StatID
|b ACS APPL MATER INTER : 2022
|d 2023-10-25
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0160
|2 StatID
|b Essential Science Indicators
|d 2023-10-25
915 _ _ |a DBCoverage
|0 StatID:(DE-HGF)0199
|2 StatID
|b Clarivate Analytics Master Journal List
|d 2023-10-25
920 _ _ |l yes
920 1 _ |0 I:(DE-Juel1)IEK-12-20141217
|k IEK-12
|l Helmholtz-Institut Münster Ionenleiter für Energiespeicher
|x 0
980 1 _ |a APC
980 1 _ |a FullTexts
980 _ _ |a journal
980 _ _ |a VDB
980 _ _ |a UNRESTRICTED
980 _ _ |a I:(DE-Juel1)IEK-12-20141217
980 _ _ |a APC
981 _ _ |a I:(DE-Juel1)IMD-4-20141217


LibraryCollectionCLSMajorCLSMinorLanguageAuthor
Marc 21