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@ARTICLE{Wagner:10251,
author = {Wagner, C. and Kasemann, D. and Golnik, C. and Forker, R.
and Esselinger, M. and Müllen, K. and Fritz, T.},
title = {{R}epulsion between molecules on a metal: {M}onolayers and
submonolayers of hexa-peri-hexabenzocoronene on {A}u(111)},
journal = {Physical review / B},
volume = {81},
number = {3},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-10251},
pages = {035423},
year = {2010},
note = {Financial support by Deutsche Forschungsgemeinschaft (DFG)
Grants No. FR875/9 and No. FR875/11 is gratefully
acknowledged.},
abstract = {We investigate the growth of hexa-peri-hexabenzocoronene
(HBC) on Au(111) for monolayer (ML) and sub-ML coverage by
scanning tunneling microscopy and low-energy electron
diffraction. A transition from a disordered isotropic phase
at low coverage to a highly ordered phase with a
coverage-dependent lattice constant at higher coverage is
found and attributed to a repulsive intermolecular force. To
deduce the origin of this repulsion a model is set up,
containing the Coulomb interaction between molecules and
between localized dipoles from the push-back effect, as well
as the intermolecular van der Waals potential. The modeling
of the van der Waals interaction is done on a force field
level. We find that the observed repulsion can only be
explained when assuming a certain screening of the
attractive London forces by the presence of the metal
substrate.},
keywords = {J (WoSType)},
cin = {IBN-3 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)VDB801 / $I:(DE-82)080009_20140620$},
pnm = {Kondensierte Materie},
pid = {G:(DE-Juel1)FUEK414},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000274002300113},
doi = {10.1103/PhysRevB.81.035423},
url = {https://juser.fz-juelich.de/record/10251},
}