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@ARTICLE{Krger:1025929,
      author       = {Kröger, Till-Niklas and Wölke, Mathis Jan and Harte,
                      Patrick and Beuse, Thomas and Winter, Martin and Nowak,
                      Sascha and Wiemers-Meyer, Simon},
      title        = {{S}tate‐of‐{C}harge {D}istribution of
                      {S}ingle‐{C}rystalline {NMC}532 {C}athodes in
                      {L}ithium‐{I}on {B}atteries: {A} {C}ritical {L}ook at the
                      {M}esoscale},
      journal      = {ChemSusChem},
      volume       = {15},
      number       = {21},
      issn         = {1864-5631},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2024-03207},
      pages        = {e202201169},
      year         = {2022},
      note         = {Unterstützt durch BMBF Projekt 03XP0237C.},
      abstract     = {The electrochemical response of layered lithium transition
                      metal oxides LiMO2 [M=Ni, Mn, Co; e. g.,
                      Li(Ni0.5Mn0.3Co0.2)O2 (NMC532)] with single-crystalline
                      architecture to slow and fast charging protocols and the
                      implication of incomplete and heterogeneous redox reactions
                      on the active material utilization during cycling were the
                      subject of this work. The role of the active material size
                      and the influence of the local microstructural and chemical
                      ramifications in the composite electrode on the evolution of
                      heterogeneous state of charge (SOC) distribution were
                      deciphered. For this, classification-single-particle
                      inductively coupled plasma optical emission spectroscopy
                      (CL-SP-ICP-OES) was comprehensively supplemented by various
                      post mortem analytical techniques. The presented results
                      question the impact of surface-dependent failure mechanisms
                      of single crystals for the evolution of SOC heterogeneity
                      and identify the deficient structural flexibility of the
                      composite electrode framework as the main driver for the
                      observed non-uniform active material utilization.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {36063139},
      UT           = {WOS:000862397700001},
      doi          = {10.1002/cssc.202201169},
      url          = {https://juser.fz-juelich.de/record/1025929},
}