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@TECHREPORT{Wilden:1030750,
author = {Wilden, Andreas and Sauerwein, Fynn Sören and Schneider,
Dimitri and Paparigas, Zaina and Henkes, Maximilian and
Modolo, Giuseppe and Baruth, Giana and Weßling, Patrik and
Geist, Andreas and Marie, Cecile and Gracia, Sophie},
title = {{PATRICIA} {D}eliverable {D}1.4 {FP} and {A}m behaviour
with new {CHON} system},
reportid = {FZJ-2024-05453},
pages = {15 p.},
year = {2024},
abstract = {A new CHON AmSEL system was developed based on PrOH-BPTD as
the americium-selective complexant. Previous investigations
(see deliverable D1.1) found it to show sufficient
efficiency and selectivity for americium over trivalent
lanthanides and curium. PrOH-BPTD is able to complex Am(III)
at nominal Am concentrations up to 20 mmol L−1 Am(III),
without precipitate of third phase formation. High
selectivity is also achieved in the presence of nominal
concentrations of Ln(III), although a saturation effect is
observed, reducing the selectivity over light lanthanides
(especially La(III)). The resistance to alpha radiolysis was
found to be excellent. The non-lanthanide fission products
Mo, Sr, Zr, and Pd could potentially be co-stripped with Am,
but can be handled using masking agents and nitric acid
scrubbing. Only Tc was found to likely follow Am, if present
in the PUREX raffinate.},
cin = {IFN-2},
cid = {I:(DE-Juel1)IFN-2-20101013},
pnm = {1412 - Predisposal (POF4-141) / PATRICIA - Partitioning And
Transmuter Research Initiative in a Collaborative Innovation
Action (945077)},
pid = {G:(DE-HGF)POF4-1412 / G:(EU-Grant)945077},
typ = {PUB:(DE-HGF)15},
url = {https://juser.fz-juelich.de/record/1030750},
}