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@ARTICLE{Krause:1041700,
author = {Krause, Hans-Joachim and Engelmann, Ulrich M.},
title = {{F}undamentals and {A}pplications of {D}ual‐{F}requency
{M}agnetic {P}article {S}pectroscopy: {R}eview for
{B}iomedicine and {M}aterials {C}haracterization},
journal = {Advanced science},
volume = {12},
number = {13},
issn = {2198-3844},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2025-02387},
pages = {2416838},
year = {2025},
note = {Open access},
abstract = {Superparamagnetic nanoparticles (MNP) offer exciting
applications for engineering and biomedicine in imaging,
diagnostics, and therapy upon magnetic excitation.
Specifically, if excited at two distinct frequencies f1 and
f2, MNP responds with magnetic intermodulation frequencies
m·f1 ± n·f2 caused by their nonlinear magnetization.
These mixing frequencies are highly specific for MNP
properties, uniquely characterizing their presence. In this
review, the fundamentals of frequency mixing magnetic
detection (FMMD) as a special case of magnetic particle
spectroscopy (MPS) are reviewed, elaborating its functional
principle that enables a large dynamic range of detection of
MNP. Mathematical descriptions derived from Langevin
modeling and micromagnetic Monte-Carlo simulations show
matching predictions. The latest applications of FMMD in
nanomaterials characterization as well as diagnostic and
therapeutic biomedicine are highlighted: analysis of the
phase of the FMMD signal characterizes the magnetic
relaxation of MNP, allowing to determine hydrodynamic size
and binding state. Variation of excitation amplitudes or
magnetic offset fields enables determining the size
distribution of the particles’ magnetic cores. This
permits multiplex detection of polydisperse MNP in magnetic
immunoassays, realized successfully for various biomolecular
targets such as viruses, bacteria, proteins, and toxins. A
portable magnetic reader enables portable immunodetection at
point-of-care. Future applications toward theranostics are
summarized and elaborated.},
cin = {IBI-3},
ddc = {624},
cid = {I:(DE-Juel1)IBI-3-20200312},
pnm = {5241 - Molecular Information Processing in Cellular Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5241},
typ = {PUB:(DE-HGF)16},
pubmed = {39985275},
UT = {WOS:001427483100001},
doi = {10.1002/advs.202416838},
url = {https://juser.fz-juelich.de/record/1041700},
}