Poster (Other)

FZJ-2025-02693

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Employing NMR techniques to explore battery interfaces and hybrid electrolytes

Barysch, V. (Corresponding author)FZJ*RWTH* ; Reina, J. V. ; Köcher, S. S.FZJ* ; Tsai, C.-L.FZJ* ; Eichel, R.-A.FZJ*RWTH* ; Scheurer, C.FZJ* ; Granwehr, J.FZJ*RWTH*

2025

Abstract: Interfaces such as those between polymers and ceramics in hybrid electrolytes are challenging to characterize by magnetic resonance:(a) Sensitivity; distinction between interface and bulk: Dynamic nuclear polarization (DNP)-enhanced NMR combined with electron paramagnetic resonance (EPR) toinvestigate electrochemically deposited lithium.(b) Interpretation: Using AlPO4 as a model system for surface structure analysis via combined magic angle spinning (MAS) NMR and density functional theory (DFT) simulations.(c) Process selectivity: 7Li exchange spectroscopy (EXSY) NMR to study ion dynamics at the polymer–ceramic interface in LLZO/PEO composites.

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Contributing Institute(s):

1. Grundlagen der Elektrochemie (IET-1)

Research Program(s):

1. 1223 - Batteries in Application (POF4-122) (POF4-122)
2. HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) (HITEC-20170406)

Appears in the scientific report 2025

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