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@ARTICLE{Tian:1043550,
author = {Tian, Jingjing and Liu, Chao and Forberich, Karen and
Barabash, Anastasia and Xie, Zhiqiang and Qiu, Shudi and
Byun, Jiwon and Peng, Zijian and Zhang, Kaicheng and DU,
Tian and Sathasivam, Sanjayan and Macdonald, Thomas J. and
Dong, Lirong and Li, Chaohui and Zhang, Jiyun and Halik,
Marcus and Le Corre, Vincent Marc and Osvet, Andres and
Heumüller, Thomas and Li, Ning and Zhou, Yinhua and Lüer,
Larry and Brabec, Christoph J.},
title = {{O}vercoming optical losses in thin metal-based
recombination layers for efficient n-i-p perovskite-organic
tandem solar cells},
journal = {Nature Communications},
volume = {16},
number = {1},
issn = {2041-1723},
address = {[London]},
publisher = {Springer Nature},
reportid = {FZJ-2025-02924},
pages = {154},
year = {2025},
abstract = {Perovskite-organic tandem solar cells (P-O-TSCs) hold
substantial potential to surpass the theoretical efficiency
limits of single-junction solar cells. However, their
performance is hampered by non-ideal interconnection layers
(ICLs). Especially in n-i-p configurations, the
incorporation of metal nanoparticles negatively introduces
serious parasitic absorption, which alleviates photon
utilization in organic rear cell and decisively constrains
the maximum photocurrent matching with front cell. Here, we
demonstrate an efficient strategy to mitigate optical losses
in Au-embedded ICLs by tailoring the shape and size
distribution of Au nanoparticles via manipulating the
underlying surface property. Achieving fewer, smaller, and
more uniformly spherical Au nanoparticles significantly
minimizes localized surface plasmon resonance absorption,
while maintaining efficient electron-hole recombination
within ICLs. Consequently, optimized P-O-TSCs combining
CsPbI2Br with various organic cells benefit from a
substantial current gain of >1.5 mA/cm2 in organic rear
cells, achieving a champion efficiency of $25.34\%.$
Meanwhile, optimized ICLs contribute to improved long-term
device stability.},
cin = {IET-2},
ddc = {500},
cid = {I:(DE-Juel1)IET-2-20140314},
pnm = {1213 - Cell Design and Development (POF4-121)},
pid = {G:(DE-HGF)POF4-1213},
typ = {PUB:(DE-HGF)16},
pubmed = {39747017},
UT = {WOS:001390013500026},
doi = {10.1038/s41467-024-55376-7},
url = {https://juser.fz-juelich.de/record/1043550},
}