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@ARTICLE{Hpkes:1046494,
author = {Hüpkes, Jürgen and Rau, Uwe and Kirchartz, Thomas},
title = {{I}mpact of {T}rap {D}epth on the {S}teady‐{S}tate and
{T}ransient {P}hotoluminescence in {H}alide {P}erovskite
{F}ilms},
journal = {Advanced energy materials},
volume = {0},
issn = {1614-6832},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2025-03833},
pages = {e03157},
year = {2025},
note = {Onlinefirst},
abstract = {Within the field of halide perovskites, trap-assisted
recombination is often considered to be synonymous with
first-order recombination, that is, recombinationthat scales
linearly with the charge-carrier concentration. However, the
standard Shockley-Read-Hall statistics naturally predict
that trap-assisted recombination can have any scaling
between linear and quadratic with carrier density, depending
on the position of the trap or defect that enables
recombination. In an intrinsic semiconductor, the shallower
a trap is, the more the recombination rate will scale
quadratically with carrier density, and the more it will
resemble radiative recombination in its behavior in any
transient experiment. Here, the theoretical implications of
the trap depth in general and shallow traps in particular on
transient and steady-state experiments applied to halide
perovskite samples for photovoltaic or optoelectronic
applications are discussed.},
cin = {IEK-5 / IMD-3},
ddc = {050},
cid = {I:(DE-Juel1)IEK-5-20101013 / I:(DE-Juel1)IMD-3-20101013},
pnm = {1215 - Simulations, Theory, Optics, and Analytics (STOA)
(POF4-121) / 1212 - Materials and Interfaces (POF4-121)},
pid = {G:(DE-HGF)POF4-1215 / G:(DE-HGF)POF4-1212},
typ = {PUB:(DE-HGF)16},
doi = {10.1002/aenm.202503157},
url = {https://juser.fz-juelich.de/record/1046494},
}