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@ARTICLE{Xiao:11329,
author = {Xiao, Y. and Su, Y. and Li, H.-F. and Kumar, C. M. N. and
Mittal, R. and Persson, J. and Senyshyn, A. and Gross, K.
and Brückel, T.},
title = {{N}eutron diffraction investigation of the crystal and
magnetic structures in {KC}r{F}3 perovskite},
journal = {Physical review / B},
volume = {82},
number = {9},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-11329},
pages = {094437},
year = {2010},
note = {Record converted from VDB: 12.11.2012},
abstract = {KCrF3 represents another prototypical orbital-ordered
perovskite, where Cr2+ possesses the same electronic
configuration of 3d(4) as that of strongly Jahn-Teller
distorted Mn3+ in many colossal magnetoresistance
manganites. The crystal and magnetic structures of KCrF3
compound are investigated by using polarized and unpolarized
neutron powder-diffraction methods. The results show that
the KCrF3 compound crystallizes in tetragonal structure at
room temperature and undergoes a monoclinic distortion with
the decrease in temperature. The distortion of the crystal
structure indicates the presence of cooperative Jahn-Teller
distortion which is driven by orbital ordering. With
decreasing temperature, four magnetic phase transitions are
observed at 79.5, 45.8, 9.5, and 3.2 K, which suggests a
rich magnetic phase diagram. Below T-N = 79.5 K, the Cr2+
moment orders in an incommensurate antiferromagnetic
arrangement, which can be defined by the magnetic
propagation vector (1/2 + delta, 1/2 + delta, 0). The
incommensurate-commensurate magnetic transition occurs at
45.8 K and the magnetic propagation vector locks into (1/2,
1/2, 0) with the Cr moment of 3.34(5) mu(B), aligned
ferromagnetically in (220) plane, but antiferromagnetically
along [110] direction. Below 9.5 K, the canted
antiferromagnetic ordering and weak ferromagnetism arise
from the collinear antiferromagnetic structure while the
Dzyaloshinskii-Moriya interaction and tilted character of
the single-ion anisotropy might give rise to the complex
magnetic behaviors below 9.5 K.},
keywords = {J (WoSType)},
cin = {IFF-4 / IFF-5 / JARA-FIT / Jülich Centre for Neutron
Science JCNS (JCNS) ; JCNS},
ddc = {530},
cid = {I:(DE-Juel1)VDB784 / I:(DE-Juel1)VDB785 /
$I:(DE-82)080009_20140620$ / I:(DE-Juel1)JCNS-20121112},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)DNS-20140101 / EXP:(DE-MLZ)SPODI-20140101},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000282097200002},
doi = {10.1103/PhysRevB.82.094437},
url = {https://juser.fz-juelich.de/record/11329},
}