Journal Article

FZJ-2013-02469

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Covalent functionalization of carbon nanotubes with tetramanganese complexes

Meyer,C. (Corresponding author) ; Besson,C. ; Frielinghaus, R. ; Saelhoff, A.-K.PGI-6*FZJ* ; Flötotto,H. ; Houben, L.FZJ* ; Schneider, C. M.FZJ*

2012
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1002/pssb.201200135

Abstract: We present first results on the covalent chemical functionalization of single-walled carbon nanotubes with polynuclear {Mn4} coordination complexes. Raman spectra prove that the reaction can only be achieved for tubes which have been oxidized to create carboxylic groups. HRTEM is used to show that the reaction can be carried out directly on a substrate as well. Analysis of the D/G intensity ratio for different oxidation times shows that it is possible to reduce the amount of defects created. This is important for the future application of this material in transport devices.

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Contributing Institute(s):

1. Mikrostrukturforschung (PGI-5)
2. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 422 - Spin-based and quantum information (POF2-422) (POF2-422)
2. 42G - Peter Grünberg-Centre (PG-C) (POF2-42G41) (POF2-42G41)

Appears in the scientific report 2012

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Database coverage:
Current Contents - Social and Behavioral Sciences ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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