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@ARTICLE{Komenda:13462,
author = {Komenda, M. and Parusel, E. and Wedel, A. and Koppmann, R.},
title = {{M}easurements of biogenic {VOC} emissions : sampling,
analysis and calibration},
journal = {Atmospheric environment},
volume = {35},
issn = {1352-2310},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-13462},
pages = {2069 - 2080},
year = {2001},
note = {Record converted from VDB: 12.11.2012},
abstract = {We describe an experimental sq stem and techniques for
sampling and analyzing biogenic emissions of volatile
organic compounds (VOC). The system uses a Teflon chamber to
enclose a single branch of a tree. Temperature,
photosynthetic active radiation (PAR), relative humidity and
carbon dioxide concentration are continuously monitored with
a time resolution of five minutes. VOCs are sampled on tubes
containing solid adsorbents (Tenax TA and Carbotrap) with a
time resolution of 1 h. Composition and concentration of VOC
emissions are measured with a gas chromatographic system
equipped with a flame ionization detector (FID) for
quantitative and a mass spectrometer (MS) for qualitative
analysis. To calibrate the system, a diffusion source was
built to produce standard mixtures of up to 36 different
compounds with mixing ratios at low concentrations and high
accuracy. The diffusion rates were monitored over 17 months
and shelved variations between 0.2 and $7.6\%$ for
monoterpenes (expect for alpha -phellandrene, alpha
-terpinene and gamma -terpinene) and between 10.6 and
$22.6\%$ for sesquiterpenes. FID response factors calculated
from calibration measurements were corrected using
correction factors based on the effective carbon number
concept. The individual response factors of 23 compounds
were combined to a mean response factor (RFm) with a value
of 23,100 muV s ng(-1) and a standard deviation of $9\%.$
The system described here was used to measure VOC emission
rates of Scots pine (Pinus sylvestris) in 1998 and 1999. (C)
2001 Elsevier Science Ltd. All rights reserved.},
keywords = {J (WoSType)},
cin = {ICG-II},
ddc = {550},
cid = {I:(DE-Juel1)VDB48},
pnm = {Troposphärische Chemie},
pid = {G:(DE-Juel1)FUEK74},
shelfmark = {Environmental Sciences / Meteorology $\&$ Atmospheric
Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000168287300003},
doi = {10.1016/S1352-2310(00)00502-1},
url = {https://juser.fz-juelich.de/record/13462},
}