Journal Article FZJ-2014-00047

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How important is Oxygen Transport in agglomerates in a PEM fuel cell catalyst layer



2014
Elsevier New York, NY [u.a.]

Electrochimica acta 130, 826-829 () [10.1016/j.electacta.2014.03.131]

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Abstract: We derive analytical solution for the polarization curve of the cathode catalyst layer (CCL), taking into account oxygen transport in agglomerates of carbon particles. The solution shows that in modern catalyst layers with agglomerates of the radius ≲100 nm, the oxygen transport in agglomerates manifests itself at cell potentials below 100 mV only. Thus, the account of this transport in CCL modeling is redundant, i.e., the standard macro–homogeneous model is adequate for CCL performance simulations.

Classification:

Contributing Institute(s):
  1. Elektrochemische Verfahrenstechnik (IEK-3)
Research Program(s):
  1. 123 - Fuel Cells (POF2-123) (POF2-123)

Appears in the scientific report 2014
Database coverage:
Medline ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Dokumenttypen > Aufsätze > Zeitschriftenaufsätze
Institutssammlungen > ICE > ICE-2
Workflowsammlungen > Öffentliche Einträge
IEK > IEK-3
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