TY  - JOUR
AU  - Klobes, Benedikt
AU  - Barrier, Nicolas
AU  - Vertruyen, Benedicte
AU  - Martin, Christine
AU  - Hermann, Raphael
TI  - Quadrupole splitting and isomer shifts in Te oxides investigated using nuclear forward scattering
JO  - Hyperfine interactions
VL  - 226
SN  - 1572-9540
CY  - Dordrecht [u.a.]
PB  - Springer Science + Business Media B.V
M1  - FZJ-2014-00422
SP  - 713
PY  - 2014
N1  - Onlinefirst
AB  - Nuclear forward scattering by 125Te is a viable alternative to conventional 125Te Mössbauer spectroscopy avoiding all source related issues. Using reference compounds with known hyperfine parameters and Te oxides exhibiting stereochemically active lone pairs, we show that nuclear forward scattering by 125Te can be reliably used to extract quadrupole splitting energy and relative isomer shift. The rough correlation between Te-Ocoordination and quadrupole splitting energy as put forward by Takeda and Greenwood (J. Chem. Soc. Dalton, 2207, 1975), is corroborated by the presented results.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000335923400084
DO  - DOI:10.1007/s10751-013-0993-4
UR  - https://juser.fz-juelich.de/record/150352
ER  -