Journal Article

FZJ-2014-00422

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Quadrupole splitting and isomer shifts in Te oxides investigated using nuclear forward scattering

Klobes, B. (Corresponding author)FZJ* ; Barrier, N. ; Vertruyen, B. ; Martin, C. ; Hermann, R.FZJ*

2014
Springer Science + Business Media B.V Dordrecht [u.a.]

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Please use a persistent id in citations: doi:10.1007/s10751-013-0993-4

Abstract: Nuclear forward scattering by 125Te is a viable alternative to conventional 125Te Mössbauer spectroscopy avoiding all source related issues. Using reference compounds with known hyperfine parameters and Te oxides exhibiting stereochemically active lone pairs, we show that nuclear forward scattering by 125Te can be reliably used to extract quadrupole splitting energy and relative isomer shift. The rough correlation between Te-Ocoordination and quadrupole splitting energy as put forward by Takeda and Greenwood (J. Chem. Soc. Dalton, 2207, 1975), is corroborated by the presented results.

Note: Onlinefirst

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Contributing Institute(s):

1. Streumethoden (JCNS-2)
2. Streumethoden (PGI-4)
3. JARA-FIT (JARA-FIT)

Research Program(s):

1. 544 - In-house Research with PNI (POF2-544) (POF2-544)
2. 54G - JCNS (POF2-54G24) (POF2-54G24)
3. 422 - Spin-based and quantum information (POF2-422) (POF2-422)
4. 424 - Exploratory materials and phenomena (POF2-424) (POF2-424)
5. 542 - Neutrons (POF2-542) (POF2-542)

Appears in the scientific report 2014

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Database coverage:
; JCR ; Nationallizenz ; SCOPUS ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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