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@ARTICLE{Klobes:150352,
      author       = {Klobes, Benedikt and Barrier, Nicolas and Vertruyen,
                      Benedicte and Martin, Christine and Hermann, Raphael},
      title        = {{Q}uadrupole splitting and isomer shifts in {T}e oxides
                      investigated using nuclear forward scattering},
      journal      = {Hyperfine interactions},
      volume       = {226},
      issn         = {1572-9540},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {FZJ-2014-00422},
      pages        = {713},
      year         = {2014},
      note         = {Onlinefirst},
      abstract     = {Nuclear forward scattering by 125Te is a viable alternative
                      to conventional 125Te Mössbauer spectroscopy avoiding all
                      source related issues. Using reference compounds with known
                      hyperfine parameters and Te oxides exhibiting
                      stereochemically active lone pairs, we show that nuclear
                      forward scattering by 125Te can be reliably used to extract
                      quadrupole splitting energy and relative isomer shift. The
                      rough correlation between Te-Ocoordination and quadrupole
                      splitting energy as put forward by Takeda and Greenwood (J.
                      Chem. Soc. Dalton, 2207, 1975), is corroborated by the
                      presented results.},
      cin          = {JCNS-2 / PGI-4 / JARA-FIT},
      ddc          = {530},
      cid          = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {544 - In-house Research with PNI (POF2-544) / 54G - JCNS
                      (POF2-54G24) / 422 - Spin-based and quantum information
                      (POF2-422) / 424 - Exploratory materials and phenomena
                      (POF2-424) / 542 - Neutrons (POF2-542)},
      pid          = {G:(DE-HGF)POF2-544 / G:(DE-HGF)POF2-54G24 /
                      G:(DE-HGF)POF2-422 / G:(DE-HGF)POF2-424 /
                      G:(DE-HGF)POF2-542},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000335923400084},
      doi          = {10.1007/s10751-013-0993-4},
      url          = {https://juser.fz-juelich.de/record/150352},
}