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000151760 1001_ $$0P:(DE-HGF)0$$aSchütte, K.$$b0$$eCorresponding author
000151760 245__ $$aSynthesis of Cu, Zn and Cu/Zn brass alloy nanoparticles from metal amidinate precursors in ionic liquids or propylene carbonate with relevance to methanol synthesis
000151760 260__ $$aCambridge$$bRSC Publ.$$c2014
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000151760 520__ $$aMicrowave-induced decomposition of the transition metal amidinates {[Me(C(NiPr)2)]Cu}2 (1) and [Me(C(NiPr)2)]2Zn (2) in the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) or in propylene carbonate (PC) gives copper and zinc nanoparticles which are stable in the absence of capping ligands (surfactants) for more than six weeks. Co-decomposition of 1 and 2 yields the intermetallic nano-brass phases β-CuZn and γ-Cu3Zn depending on the chosen molar ratios of the precursors. Nanoparticles were characterized by high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM), dynamic light scattering and powder X-ray diffractometry. Microstructure characterizations were complemented by STEM with spatially resolved energy-dispersive X-ray spectrometry and X-ray photoelectron spectroscopy. Synthesis in ILs yields significantly smaller nanoparticles than in PC. β-CuZn alloy nanoparticles are precursors to catalysts for methanol synthesis from the synthesis gas H2/CO/CO2 with a productivity of 10.7 mol(MeOH) (kg(Cu) h)−1.
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000151760 7001_ $$0P:(DE-HGF)0$$aMeyer, H.$$b1
000151760 7001_ $$0P:(DE-HGF)0$$aGemel, Chr.$$b2
000151760 7001_ $$0P:(DE-Juel1)130525$$aBarthel, Juri$$b3$$ufzj
000151760 7001_ $$0P:(DE-HGF)0$$aFischer, R. A.$$b4
000151760 7001_ $$0P:(DE-HGF)0$$aJaniak, Chr.$$b5
000151760 773__ $$0PERI:(DE-600)2515664-0$$a10.1039/C3NR05780A$$n6$$p3116 - 3126$$tNanoscale$$v6$$x2040-3364
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000151760 9132_ $$0G:(DE-HGF)POF3-529H$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vAddenda$$x0
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