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| 037 | _ | _ | |a FZJ-2014-01649 |
| 041 | _ | _ | |a English |
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| 100 | 1 | _ | |a Schütte, K. |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Synthesis of Cu, Zn and Cu/Zn brass alloy nanoparticles from metal amidinate precursors in ionic liquids or propylene carbonate with relevance to methanol synthesis |
| 260 | _ | _ | |a Cambridge |c 2014 |b RSC Publ. |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 151760 |2 PUB:(DE-HGF) |
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| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 520 | _ | _ | |a Microwave-induced decomposition of the transition metal amidinates {[Me(C(NiPr)2)]Cu}2 (1) and [Me(C(NiPr)2)]2Zn (2) in the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) or in propylene carbonate (PC) gives copper and zinc nanoparticles which are stable in the absence of capping ligands (surfactants) for more than six weeks. Co-decomposition of 1 and 2 yields the intermetallic nano-brass phases β-CuZn and γ-Cu3Zn depending on the chosen molar ratios of the precursors. Nanoparticles were characterized by high-angle annular dark field-scanning transmission electron microscopy (HAADF-STEM), dynamic light scattering and powder X-ray diffractometry. Microstructure characterizations were complemented by STEM with spatially resolved energy-dispersive X-ray spectrometry and X-ray photoelectron spectroscopy. Synthesis in ILs yields significantly smaller nanoparticles than in PC. β-CuZn alloy nanoparticles are precursors to catalysts for methanol synthesis from the synthesis gas H2/CO/CO2 with a productivity of 10.7 mol(MeOH) (kg(Cu) h)−1. |
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| 700 | 1 | _ | |a Meyer, H. |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Gemel, Chr. |0 P:(DE-HGF)0 |b 2 |
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| 700 | 1 | _ | |a Fischer, R. A. |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Janiak, Chr. |0 P:(DE-HGF)0 |b 5 |
| 773 | _ | _ | |a 10.1039/C3NR05780A |0 PERI:(DE-600)2515664-0 |n 6 |p 3116 - 3126 |t Nanoscale |v 6 |x 2040-3364 |
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