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| Home > Publications database > Influence of the Ba$^{2+}$/Sr$^{2+}$ Content and Oxygen Vacancies on the Stability of Cubic Ba$_{x}$Sr$_{1-x}$Co$_{0.75}$Fe$_{0.25}$O$_{3−δ}$ |
| Journal Article | FZJ-2014-03518 |
; ; ; ; ; ; ;
2014
RSC Publ.
Cambridge
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Please use a persistent id in citations: doi:10.1039/c3cp53958j
Abstract: We present a theoretical and experimental study on the influence ofthe Ba/Sr and Co/Fe ratios as well as the oxygen-non-stoichiometry onthe stability of Ba0.5Sr0.5Co0.8Fe0.2O3d (BSCF). Thin-layer depositionsare analysed by looking at TEM images and EDX spectra. Bondanalyticalcalculations are performed to explain the stability differencebetween hexagonal and cubic BSCF. Finally, annealing experimentsanalysed using XRD give an insight into the differences of phasefractiongrowth with respect to the Ba/Sr ratio.
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