TY - JOUR
AU - Yazdanbakhsh, F.
AU - Bläsing, Marc
AU - Sawada, J.
AU - Rezaei, S.
AU - Müller, Michael
AU - Baumann, Stefan
TI - Copper Exchanged Nanotitanate for High Temperature H2S Adsorption
JO - Industrial and engineering chemistry / Product research and development
VL - 53
SN - 1541-4841
CY - Easton, Pa.
PB - Soc.
M1 - FZJ-2014-05161
SP - 11734-11739
PY - 2014
AB - The H2S breakthrough capacity of copper-exchanged Engelhard Titanosilicate-2 (ETS-2) was measured attemperatures up to 950 °C and it was found that the adsorbent efficiency remains unchanged across the entire temperaturerange. Below 750 °C, the adsorption capacity at breakthrough is 0.7 mol of H2S per mole of copper while above 750 °C thecapacity of the adsorbent is halved. The change in H2S capacity is due to Cu2+ reduction by the H2 which is formed through thethermal dissociation of H2S. The adsorbent shows good potential for use over a wide range of operating temperatures in H2Sscrubbing processes.
LB - PUB:(DE-HGF)16
UR - https://juser.fz-juelich.de/record/156418
ER -