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|a 10.1071/CH11173
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041 _ _ |a eng
082 _ _ |a 540
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|a Chemistry, Multidisciplinary
100 1 _ |0 P:(DE-HGF)0
|a Weidner, T.
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245 _ _ |a NHC-based self-asssembled monolayers on solid gold substrates
260 _ _ |a Melbourne
|b CSIRO
|c 2011
300 _ _ |a 1177
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|a Australian Journal of Chemistry
|v 64
|y 8
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a This work was funded in part by NESAC-BIO (NIH grant EB-002027). T. W. thanks the Deutsche Forschungsgemeinschaft for a research fellowship. T. W. and J. E. B. thank David G. Castner for support and Daniel Fischer and Cherno Jaye (NIST) for providing them with the experimental equipment for NEXAFS spectroscopy and their help at the synchrotron. NEXAFS studies were performed at the NSLS, Brookhaven National Laboratory, which is supported by the USA Department of Energy, Division of Materials Science and Division of Chemical Sciences.
520 _ _ |a Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)(2) was also determined.
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|t Australian journal of chemistry
|v 64
|x 0004-9425
|y 2011
856 7 _ |u http://dx.doi.org/10.1071/CH11173
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