Journal Article PreJuSER-16722

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NHC-based self-asssembled monolayers on solid gold substrates

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2011
CSIRO Melbourne

Australian journal of chemistry 64, 1177 () [10.1071/CH11173]

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Abstract: Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)(2) was also determined.

Keyword(s): J


Note: This work was funded in part by NESAC-BIO (NIH grant EB-002027). T. W. thanks the Deutsche Forschungsgemeinschaft for a research fellowship. T. W. and J. E. B. thank David G. Castner for support and Daniel Fischer and Cherno Jaye (NIST) for providing them with the experimental equipment for NEXAFS spectroscopy and their help at the synchrotron. NEXAFS studies were performed at the NSLS, Brookhaven National Laboratory, which is supported by the USA Department of Energy, Division of Materials Science and Division of Chemical Sciences.

Contributing Institute(s):
  1. Elektronische Materialien (PGI-7)
  2. Jülich-Aachen Research Alliance - Fundamentals of Future Information Technology (JARA-FIT)
Research Program(s):
  1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2011
Database coverage:
JCR ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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JARA > JARA > JARA-JARA\-FIT
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 Record created 2012-11-13, last modified 2019-06-25



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