%0 Journal Article
%A Izarova, Natalya
%A Maksimovskaya, Raisa I.
%A Willbold, Sabine
%A Kögerler, Paul
%T Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study
%J Inorganic chemistry
%V 53
%N 21
%@ 1520-510X
%C Washington, DC
%I American Chemical Society
%M FZJ-2014-05591
%P 11778–11784
%D 2014
%X The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16– has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV–vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000344307400048
%$ pmid:25325671
%R 10.1021/ic502080x
%U https://juser.fz-juelich.de/record/172042