Journal Article

FZJ-2014-05591

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study

Izarova, N.FZJ* ; Maksimovskaya, R. I. ; Willbold, S.FZJ* ; Kögerler, P. (Corresponding Author)FZJ*

2014
American Chemical Society Washington, DC

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Please use a persistent id in citations: http://hdl.handle.net/2128/8057  http://hdl.handle.net/2128/9140  doi:10.1021/ic502080x

Abstract: The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16– has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV–vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)
2. Analytik (ZEA-3)

Research Program(s):

1. 424 - Exploratory materials and phenomena (POF2-424) (POF2-424)

Appears in the scientific report 2014

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Database coverage:
; ; ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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