TY  - JOUR
AU  - Izarova, Natalya
AU  - Maksimovskaya, Raisa I.
AU  - Willbold, Sabine
AU  - Kögerler, Paul
TI  - Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study
JO  - Inorganic chemistry
VL  - 53
IS  - 21
SN  - 1520-510X
CY  - Washington, DC
PB  - American Chemical Society
M1  - FZJ-2014-05591
SP  - 11778–11784
PY  - 2014
AB  - The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16– has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV–vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000344307400048
C6  - pmid:25325671
DO  - DOI:10.1021/ic502080x
UR  - https://juser.fz-juelich.de/record/172042
ER  -