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@ARTICLE{Izarova:172042,
      author       = {Izarova, Natalya and Maksimovskaya, Raisa I. and Willbold,
                      Sabine and Kögerler, Paul},
      title        = {{T}etrapalladium-{C}ontaining {P}olyoxotungstate
                      [${P}d^{{II}}_4$(α-${P}_2{W}_{15}{O}_{56})_2$]${}^{16–}$:
                      {A} {C}omparative {S}tudy},
      journal      = {Inorganic chemistry},
      volume       = {53},
      number       = {21},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2014-05591},
      pages        = {11778–11784},
      year         = {2014},
      abstract     = {The novel tetrapalladium(II)-containing polyoxometalate
                      [PdII4(α-P2W15O56)2]16– has been prepared in aqueous
                      medium and characterized as its hydrated sodium salt
                      Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD,
                      elemental analysis, IR, Raman, multinuclear NMR, and
                      UV–vis spectroscopy. The complex exists in anti and syn
                      conformations, which form in a 2:1 ratio, and possesses
                      unique structural characteristics in comparison with known
                      {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are
                      consistent with the long-term stability of the both isomers
                      in aqueous solutions.},
      cin          = {PGI-6 / ZEA-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106 / I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {424 - Exploratory materials and phenomena (POF2-424)},
      pid          = {G:(DE-HGF)POF2-424},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000344307400048},
      pubmed       = {pmid:25325671},
      doi          = {10.1021/ic502080x},
      url          = {https://juser.fz-juelich.de/record/172042},
}