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| Home > Publications database > Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study > print |
| Home > Publications database > Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study > print |
| 001 | 172042 | ||
| 005 | 20210129214348.0 | ||
| 024 | 7 | _ | |a 10.1021/ic502080x |2 doi |
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| 037 | _ | _ | |a FZJ-2014-05591 |
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| 100 | 1 | _ | |a Izarova, Natalya |0 P:(DE-Juel1)157892 |b 0 |
| 245 | _ | _ | |a Tetrapalladium-Containing Polyoxotungstate [$Pd^{II}_4$(α-$P_2W_{15}O_{56})_2$]${}^{16–}$: A Comparative Study |
| 260 | _ | _ | |a Washington, DC |c 2014 |b American Chemical Society |
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| 520 | _ | _ | |a The novel tetrapalladium(II)-containing polyoxometalate [PdII4(α-P2W15O56)2]16– has been prepared in aqueous medium and characterized as its hydrated sodium salt Na16[Pd4(α-P2W15O56)2]·71H2O by single-crystal XRD, elemental analysis, IR, Raman, multinuclear NMR, and UV–vis spectroscopy. The complex exists in anti and syn conformations, which form in a 2:1 ratio, and possesses unique structural characteristics in comparison with known {M4(P2W15)2} species. 31P and 183W NMR spectroscopy are consistent with the long-term stability of the both isomers in aqueous solutions. |
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| 700 | 1 | _ | |a Kögerler, Paul |0 P:(DE-Juel1)130782 |b 3 |e Corresponding Author |
| 773 | _ | _ | |a 10.1021/ic502080x |g p. 141017134855000 - |0 PERI:(DE-600)1484438-2 |n 21 |p 11778–11784 |t Inorganic chemistry |v 53 |y 2014 |x 1520-510X |
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