Hauptseite > Publikationsdatenbank > Enhanced oxidation resistance of ZrB$_{2}$/SiC Composite through in situ reaction of gadolinium oxide in patterned surface cavities |
Journal Article | FZJ-2015-00690 |
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2014
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.jeurceramsoc.2014.07.015
Abstract: Micro-cavities on the surface of dense ZrB2/20 vol.% SiC composites, machined by ultra-fast laser ablation, were filled with Gd2O3 nanopowder and oxidized in static air at 1600 °C. Optimized rectangular pattern of cavities, 10 μm diameter and deep, 20 μm apart conferred improved oxidation resistance compared to the untreated ZrB2/20 vol.% SiC due to the formation of glasses of higher viscosity with lower oxygen diffusivities. Reduction of the oxidized depth was revealed by a significant decrease of 10 μm (60%) in the extent of the protective layer. The filled-cavity strategy leads to better protection against oxygen diffusivity into the composite without altering the bulk properties.
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