Journal Article FZJ-2015-00720

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Microstructural variations and their influence on the performance of solid oxide fuel cells based on yttrium-substituted strontium titanate ceramic anodes

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2015
Elsevier New York, NY [u.a.]

Journal of power sources 279, 678 - 685 () [10.1016/j.jpowsour.2015.01.063]

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Abstract: Donor-substituted strontium titanates have been widely recognised as alternative anode materials to the state-of-the-art Ni/YSZ cermets in solid oxide fuel cells (SOFCs). Electrolyte-supported SOFCs based on Y0.07Sr0.895TiO3 ceramic anodes with different microstructural designs were prepared. Ni or Ni with Ce0.8Gd0.2O1.9 (CGO) was infiltrated onto the pore walls within the ceramic anode framework as an electrocatalyst for anode reactions. Performances and electrochemical impedance spectroscopy measurements of the cells were analysed in detail to observe the influence of low ionic conductivity of Y0.07Sr0.895TiO3 to cell performance, to understand how to control the degradation of the cells, and to obtain a possible mechanism for the anode processes. The anode design containing both functional and current collecting layers with sufficient Ni-CGO infiltration is favourable for high power output and low performance degradation.

Classification:

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
Research Program(s):
  1. 135 - Fuel Cells (POF3-135) (POF3-135)

Appears in the scientific report 2015
Database coverage:
Medline ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2015-01-21, last modified 2024-07-11


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