Journal Article FZJ-2015-01993

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Mechanical properties of pure and doped cerium oxide

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2015
Elsevier Science Amsterdam [u.a.]

Journal of the European Ceramic Society 35(5), 1539-1547 () [10.1016/j.jeurceramsoc.2014.11.036]

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Abstract: Advanced concepts for oxygen transport membranes focus on thin layers supported by a porous substrate. To warrant long term reliable operation of such systems, an assessment of the mechanical stability of each membrane component is required. With respect to chemical stability, cerium oxide and doped cerium oxides are promising materials for this application. The present work addresses the mechanical properties of cerium oxide variants, aiming to elucidate properties of relevance to the manufacture of reliable cerium oxide components. In particular Ce0.8Gd0.2−yPryO2−δ membrane materials and the influence of an addition 2 mol% of CoO is assessed. Materials preparation and compositional variations are compared with respect to elastic modulus, hardness and fracture toughness, as characterized using depth sensitive indentation. Furthermore, the creep behavior of doped and undoped cerium oxides, that is important for the long term structural stability at temperatures relevant to the oxygen-membranes operation, is assessed and critically discussed.

Classification:

Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
  2. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
Research Program(s):
  1. 111 - Efficient and Flexible Power Plants (POF3-111) (POF3-111)

Appears in the scientific report 2015
Database coverage:
Medline ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Dokumenttypen > Aufsätze > Zeitschriftenaufsätze
Institutssammlungen > IMD > IMD-2
Institutssammlungen > IMD > IMD-1
Workflowsammlungen > Öffentliche Einträge
IEK > IEK-2
IEK > IEK-1
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