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024 7 _ |a 1873-2453
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100 1 _ |a Jeangros, Q.
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245 _ _ |a Oxidation mechanism of nickel particles studied in an environmental transmission electron microscope
260 _ _ |a Amsterdam [u.a.]
|c 2014
|b Elsevier Science
336 7 _ |a Journal Article
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520 _ _ |a The oxidation of nickel particles was studied in situ in an environmental transmission electron microscope in 3.2 mbar of O2 between ambient temperature and 600 °C. Several different transmission electron microscopy imaging techniques, electron diffraction and electron energy-loss spectroscopy were used to study the evolution of the microstructure and the local chemical composition of the particles during oxidation. Our results suggest that built-in field effects control the initial stages of oxidation, with randomly oriented NiO crystallites and internal voids then forming as a result of outward diffusion of Ni2+ along NiO grain boundaries, self-diffusion of Ni2+ ions and vacancies, growth of NiO grains and nucleation of voids at Ni/NiO interfaces. We also observed the formation of transverse cracks in a growing NiO film in situ in the electron microscope.
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700 1 _ |a Hansen, T. W.
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700 1 _ |a Wagner, J. B.
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700 1 _ |a Dunin-Borkowski, Rafal
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700 1 _ |a Hébert, C.
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700 1 _ |a Van herle, J.
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700 1 _ |a Hessler-Wyser, A.
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773 _ _ |a 10.1016/j.actamat.2013.12.035
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|t Acta materialia
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