TY - JOUR AU - Schuck, Martin AU - Rieß, Sally AU - Schreiber, Marcel AU - Mussler, Gregor AU - Grützmacher, Detlev AU - Hardtdegen, Hilde TI - Metal organic vapor phase epitaxy of hexagonal Ge–Sb–Te (GST) JO - Journal of crystal growth VL - 420 SN - 0022-0248 CY - Amsterdam [u.a.] PB - Elsevier M1 - FZJ-2015-02661 SP - 37 - 41 PY - 2015 AB - Epitaxial, hexagonal Ge–Sb–Te was grown on Si(111)Si(111) substrates by Metal Organic Vapor Phase Epitaxy (MOVPE) using the precursor digermane. The effect of reactor pressure, growth temperature and in situ pre-treatment on morphology and Ge–Sb–Te composition was studied. The composition is sensitive to reactor pressure and growth temperature. Compositional control is achieved at a reactor pressure of View the MathML source50hPa. Substrate pre-treatment affects film coalescence. The use of hydrogen and a suitable precursor pre-treatment leads to enhanced surface coverage. X-ray diffraction reveals a trigonal structure with lattice parameters close to that reported for Ge1Sb2Te4Ge1Sb2Te4 crystallizing in the View the MathML sourceR3¯m phase. The composition was confirmed by energy-dispersive X-ray spectroscopy. LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000353825100007 DO - DOI:10.1016/j.jcrysgro.2015.03.034 UR - https://juser.fz-juelich.de/record/189504 ER -