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000019962 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000019962 1001_ $$0P:(DE-HGF)0$$aMiras, H.N.$$b0
000019962 245__ $$aExploring the Structure and Properties of Transition Metal Templated {VM(17)(VO(4))(2)} Dawson-Like Capsules
000019962 260__ $$aWeinheim$$bWiley-VCH$$c2011
000019962 300__ $$a8384 - 8391
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000019962 440_0 $$011961$$aEuropean Journal of Inorganic Chemistry$$v50$$x1434-1948$$y17
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000019962 500__ $$aWe thank the ESPRC, WestCHEM, the University of Glasgow, and the multifrequency EPR Service (Manchester). H.N.M. thanks the Royal Society of Edinburgh and Marie Curie Actions for the financial support. L.C. thanks the Royal Society and Wolfson Foundation for a merit award.
000019962 520__ $$aVanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM(17)}-type shell, which was corroborated by EPR and theoretical studies.
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000019962 7001_ $$0P:(DE-HGF)0$$aStone, D.$$b1
000019962 7001_ $$0P:(DE-HGF)0$$aLong, D.L.$$b2
000019962 7001_ $$0P:(DE-HGF)0$$aMcInnes, E.J.L$$b3
000019962 7001_ $$0P:(DE-Juel1)VDB104778$$aKogerler, P.$$b4$$uFZJ
000019962 7001_ $$0P:(DE-HGF)0$$aCronin, L.$$b5
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000019962 8567_ $$uhttp://dx.doi.org/10.1021/ic200943s
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