Journal Article

PreJuSER-19962

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Exploring the Structure and Properties of Transition Metal Templated {VM(17)(VO(4))(2)} Dawson-Like Capsules

Miras, H. N. ; Stone, D. ; Long, D. L. ; McInnes, E. J. L ; Kogerler, P.FZJ* ; Cronin, L.

2011
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1021/ic200943s

Abstract: Vanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM(17)}-type shell, which was corroborated by EPR and theoretical studies.

Keyword(s): J

Note: We thank the ESPRC, WestCHEM, the University of Glasgow, and the multifrequency EPR Service (Manchester). H.N.M. thanks the Royal Society of Edinburgh and Marie Curie Actions for the financial support. L.C. thanks the Royal Society and Wolfson Foundation for a merit award.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2011

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