TY  - JOUR
AU  - Miras, H.N.
AU  - Stone, D.
AU  - Long, D.L.
AU  - McInnes, E.J.L
AU  - Kogerler, P.
AU  - Cronin, L.
TI  - Exploring the Structure and Properties of Transition Metal Templated {VM(17)(VO(4))(2)} Dawson-Like Capsules
JO  - European journal of inorganic chemistry
VL  - 50
SN  - 1434-1948
CY  - Weinheim
PB  - Wiley-VCH
M1  - PreJuSER-19962
SP  - 8384 - 8391
PY  - 2011
N1  - We thank the ESPRC, WestCHEM, the University of Glasgow, and the multifrequency EPR Service (Manchester). H.N.M. thanks the Royal Society of Edinburgh and Marie Curie Actions for the financial support. L.C. thanks the Royal Society and Wolfson Foundation for a merit award.
AB  - Vanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM(17)}-type shell, which was corroborated by EPR and theoretical studies.
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
C6  - pmid:21793492
UR  - <Go to ISI:>//WOS:000294242700061
DO  - DOI:10.1021/ic200943s
UR  - https://juser.fz-juelich.de/record/19962
ER  -