Journal Article

PreJuSER-19965

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png {Fe(6)O(2)}-Based Assembly of a Tetradecanuclear Iron Nanocluster

Baca, S. G. ; Speldrich, M. ; Ellern, A. ; Kogerler, P.FZJ*

2011
Trans Tech Publ. Uetikon

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Please use a persistent id in citations: doi:10.3390/ma4010300

Abstract: The tetradecanuclear Fe-III pivalate nanocluster [Fe14O10(OH)(4)(Piv)(18)], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.

Keyword(s): J ; Iron(III) carboxylates (auto) ; Solvothermal synthesis (auto) ; X-ray structure (auto) ; Magnetic properties (auto)

Note: Financial support was provided by the German Federal Ministry of Education and Research (Grant MDA 08/022) and the Academy of Sciences of Moldova (Grant No. 09.820.05.10GF). We thank the European Commision for a IIF Marie Curie Fellowship to S.G.B. (POLYMAG, contract no. 252984).

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. Grundlagen für zukünftige Informationstechnologien (P42)
2. POLYMAG - Magnetic Coordination Cluster Polymers (252984) (252984)

Appears in the scientific report 2011

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