Journal Article

FZJ-2015-03818

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Pressure dependence of the tin–phosphorus phase diagram

Ritscher, A. ; Schmetterer, C.FZJ* ; Ipser, H. (Corresponding Author)

2012
Springer Wien [u.a.]

This record in other databases:    

Please use a persistent id in citations: doi:10.1007/s00706-012-0861-y

Abstract: The pressure dependence of the binary Sn–P phase diagram was investigated using an isopiestic equilibration method. Successful experiments were carried out at nine different pressures in the range from 0.006 to 0.69 bar, and the corresponding phase diagrams for these pressures were created up to a content of x P = 70 %. The change of the equilibrium temperatures of the formation reactions for the three binary compounds (Sn4P3, Sn3P4, SnP3) with increasing pressure was analyzed and extrapolated to 1 bar. The pressure-dependent maximum solubility of phosphorus in the tin-rich liquid was investigated and partial thermodynamic properties of P were derived for the liquid phase. Standard molar Gibbs energies of formation were derived for all three stable compounds.

---

Contributing Institute(s):

1. Werkstoffstruktur und -eigenschaften (IEK-2)

Research Program(s):

1. 122 - Power Plants (POF2-122) (POF2-122)

---

Database coverage:
; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

---