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@ARTICLE{LopezHilfiker:202063,
author = {Lopez-Hilfiker, F. D. and Mohr, C. and Ehn, M. and Rubach,
F. and Kleist, E. and Wildt, J. and Mentel, Th. F. and Lutz,
Anna and Hallquist, M. and Worsnop, D. and Thornton, J. A.},
title = {{A} novel method for online analysis of gas and particle
composition: description and evaluation of a {F}ilter
{I}nlet for {G}ases and {AERO}sols ({FIGAERO})},
journal = {Atmospheric measurement techniques},
volume = {7},
number = {4},
issn = {1867-8548},
address = {Katlenburg-Lindau},
publisher = {Copernicus},
reportid = {FZJ-2015-04352},
pages = {983 - 1001},
year = {2014},
abstract = {We describe a novel inlet that allows measurement of both
gas and particle molecular composition when coupled to mass
spectrometric, chromatographic, or optical sensors: the
Filter Inlet for Gases and AEROsols (FIGAERO). The design
goals for the FIGAERO are to allow unperturbed observation
of ambient air while simultaneously analyzing gases and
collecting particulate matter on a Teflon® (hereafter
Teflon) filter via an entirely separate sampling port. The
filter is analyzed periodically by the same sensor on hourly
or faster timescales using temperature-programmed thermal
desorption. We assess the performance of the FIGAERO by
coupling it to a high-resolution time-of-flight
chemical-ionization mass spectrometer (HRToF-CIMS) in
laboratory chamber studies of α-pinene oxidation and field
measurements at a boreal forest location. Low instrument
backgrounds give detection limits of ppt or lower for
compounds in the gas-phase and in the picogram m−3 range
for particle phase compounds. The FIGAERO-HRToF-CIMS
provides molecular information about both gases and particle
composition on the 1 Hz and hourly timescales, respectively
for hundreds of compounds. The FIGAERO thermal desorptions
are highly reproducible (better than $10\%),$ allowing a
calibrated assessment of the effective volatility of
desorbing compounds and the role of thermal decomposition
during the desorption process. We show that the often
multi-modal desorption thermograms arising from secondary
organic aerosol (SOA) provide additional insights into
molecular composition and/or particle morphology, and
exhibit changes with changes in SOA formation or aging
pathways.},
cin = {IEK-8 / IBG-2},
ddc = {550},
cid = {I:(DE-Juel1)IEK-8-20101013 / I:(DE-Juel1)IBG-2-20101118},
pnm = {233 - Trace gas and aerosol processes in the troposphere
(POF2-233)},
pid = {G:(DE-HGF)POF2-233},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000335373600008},
doi = {10.5194/amt-7-983-2014},
url = {https://juser.fz-juelich.de/record/202063},
}