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@INPROCEEDINGS{Richter:202709,
author = {Richter, Alexei and Zhao, Lei and Finger, Friedhelm and
Ding, Kaining},
title = {{M}icrostructure {M}odel for {H}ydrogenated
{N}anocrystalline {S}ilicon {O}xide {T}hin-{F}ilms in
{S}ilicon {H}eterojunction {S}olar {C}ells},
reportid = {FZJ-2015-04892},
year = {2015},
abstract = {A straightforward approach to increase the solar energy
conversion efficiency in solar cells is to reduce their
optical loss while maintaining the electrical performance.
For example, nanocrystalline hydrogenated silicon oxide (nc
SiOX:H) can be implemented in silicon based solar cells as a
wide optical band gap material to diminish parasitic optical
losses. At the same time, an excellent electrical
conductivity can be achieved due to its unique
microstructure. In the present work, we introduce a
microstructure model that consistently correlates the nc
SiOX:H microstructure, consisting of four different phases,
to the deposition conditions during Plasma Enhanced Chemical
Vapour Deposition (PECVD) as well as to the optoelectronic
properties of nc SiOX:H thin films. We successfully
validated the model by means of a large quantity of
systematically and individually optimized n- and p-doped nc
SiOX:H films deposited at very high frequency (VHF) and
radio frequency (RF). In particular, this model shows that
the improved optoelectronic performance of nc SiOX:H films
deposited at VHF as compared to RF might be a consequence of
an improved phase separation between the conductive
nanocrystalline silicon and the oxygen rich matrix at VHF,
which in turn is likely due to a higher hydrogen etching
effect as compared to RF. In addition, we present our newest
results on silicon heterojunction solar cells using our
newly developed VHF nc SiOX:H with superior optoelectronic
properties.},
month = {Jun},
date = {2015-06-15},
organization = {42nd IEEE Photovoltaic Specialists
Conference, New Orleans (USA), 15 Jun
2015 - 19 Jun 2015},
subtyp = {Other},
cin = {IEK-5},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121) / HITEC
- Helmholtz Interdisciplinary Doctoral Training in Energy
and Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-121 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/202709},
}