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@ARTICLE{Mairoser:202798,
author = {Mairoser, Thomas and Mundy, Julia A. and Melville,
Alexander and Hodash, Daniel and Cueva, Paul and Held,
Rainer and Glavic, Artur and Schubert, Jürgen and Muller,
David A. and Schlom, Darrell G. and Schmehl, Andreas},
title = {{H}igh-quality {E}u{O} thin films the easy way via
topotactic transformation},
journal = {Nature Communications},
volume = {6},
issn = {2041-1723},
address = {London},
publisher = {Nature Publishing Group},
reportid = {FZJ-2015-04967},
pages = {7716 -},
year = {2015},
abstract = {Epitaxy is widely employed to create highly oriented
crystalline films. A less appreciated, butnonetheless
powerful means of creating such films is via topotactic
transformation, in which achemical reaction transforms a
single crystal of one phase into a single crystal of a
differentphase, which inherits its orientation from the
original crystal. Topotactic reactions may beapplied to
epitactic films to substitute, add or remove ions to yield
epitactic films of differentphases. Here we exploit a
topotactic reduction reaction to provide a non-ultra-high
vacuum(UHV) means of growing highly oriented single
crystalline thin films of the easily
overoxidizedhalf-metallic semiconductor europium monoxide
(EuO) with a perfection rivallingthat of the best films of
the same material grown by molecular-beam epitaxy or UHV
pulsedlaserdeposition. As the technique only requires
high-vacuum deposition equipment, it hasthe potential to
drastically improve the accessibility of high-quality single
crystalline films ofEuO as well as other
difficult-to-synthesize compounds.},
cin = {PGI-9 / JARA-FIT},
ddc = {500},
cid = {I:(DE-Juel1)PGI-9-20110106 / $I:(DE-82)080009_20140620$},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000358858500022},
pubmed = {pmid:26177710},
doi = {10.1038/ncomms8716},
url = {https://juser.fz-juelich.de/record/202798},
}