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037 _ _ |a PreJuSER-20874
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082 _ _ |a 690
084 _ _ |2 WoS
|a Chemistry, Multidisciplinary
084 _ _ |2 WoS
|a Energy & Fuels
084 _ _ |2 WoS
|a Engineering, Chemical
084 _ _ |2 WoS
|a Environmental Sciences
100 1 _ |0 P:(DE-HGF)0
|a Zhi, M.
|b 0
245 _ _ |a An intermediate-temperature solid oxide fuel cell with electrospun nanofiber cathode
260 _ _ |a Cambridge
|b RSC Publ.
|c 2012
300 _ _ |a 7066 - 7071
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440 _ 0 |0 25783
|a Energy & Environmental Science
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500 _ _ |a This work was supported by the National Energy Technology Laboratory's on-going research in fuel cell project DE-FE0000400 under the URS Corporation contract and West Virginia State Research Challenge Grant Energy Materials Program (EPS08-01). The authors are grateful for the helpful discussion with Dr Kirk Gerdes at NETL and Fanke Meng and Savan Suri at WVU for characterization assistance.
520 _ _ |a Lanthanum strontium cobalt ferrite (LSCF) nanofibers have been fabricated by the electrospinning method and used as the cathode of an intermediate-temperature solid oxide fuel cell (SOFC) with yttria-stabilized zirconia (YSZ) electrolyte. The three-dimensional nanofiber network cathode has several advantages: (i) high porosity; (ii) high percolation; (iii) continuous pathway for charge transport; (iv) good thermal stability at the operating temperature; and (v) excellent scaffold for infiltration. The fuel cell with the monolithic LSCF nanofiber cathode exhibits a power density of 0.90 W cm(-2) at 1.9 A cm(-2) at 750 degrees C. The electrochemical performance of the fuel cell has been further improved by infiltration of 20 wt% of gadolinia-doped ceria (GDC) into the LSCF nanofiber cathode. The fuel cell with the LSCF-20% GDC composite cathode shows a power density of 1.07 W cm(-2) at 1.9 A cm(-2) at 750 degrees C. The results obtained show that one-dimensional nanostructures such as nanofibers hold great promise as electrode materials for intermediate-temperature SOFCs.
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