Journal Article PreJuSER-20874

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An intermediate-temperature solid oxide fuel cell with electrospun nanofiber cathode

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2012
RSC Publ. Cambridge

Energy & environmental science 5, 7066 - 7071 () [10.1039/c2ee02619h]

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Abstract: Lanthanum strontium cobalt ferrite (LSCF) nanofibers have been fabricated by the electrospinning method and used as the cathode of an intermediate-temperature solid oxide fuel cell (SOFC) with yttria-stabilized zirconia (YSZ) electrolyte. The three-dimensional nanofiber network cathode has several advantages: (i) high porosity; (ii) high percolation; (iii) continuous pathway for charge transport; (iv) good thermal stability at the operating temperature; and (v) excellent scaffold for infiltration. The fuel cell with the monolithic LSCF nanofiber cathode exhibits a power density of 0.90 W cm(-2) at 1.9 A cm(-2) at 750 degrees C. The electrochemical performance of the fuel cell has been further improved by infiltration of 20 wt% of gadolinia-doped ceria (GDC) into the LSCF nanofiber cathode. The fuel cell with the LSCF-20% GDC composite cathode shows a power density of 1.07 W cm(-2) at 1.9 A cm(-2) at 750 degrees C. The results obtained show that one-dimensional nanostructures such as nanofibers hold great promise as electrode materials for intermediate-temperature SOFCs.

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Note: This work was supported by the National Energy Technology Laboratory's on-going research in fuel cell project DE-FE0000400 under the URS Corporation contract and West Virginia State Research Challenge Grant Energy Materials Program (EPS08-01). The authors are grateful for the helpful discussion with Dr Kirk Gerdes at NETL and Fanke Meng and Savan Suri at WVU for characterization assistance.

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellverfahren (IEK-1)
Research Program(s):
  1. Rationelle Energieumwandlung (P12)
  2. SOFC - Solid Oxide Fuel Cell (SOFC-20140602) (SOFC-20140602)

Appears in the scientific report 2012
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OpenAccess by Allianz-OA ; Allianz-Lizenz / DFG ; BIOSIS Previews ; Current Contents - Agriculture, Biology and Environmental Sciences ; Current Contents - Physical, Chemical and Earth Sciences ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2012-11-13, last modified 2024-07-11


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