Home > Publications database > Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC |
Journal Article | PreJuSER-21033 |
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2012
Elsevier
New York, NY [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.ijhydene.2011.11.002
Abstract: The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H-2. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Keyword(s): J ; Solid oxide fuel cells (auto) ; Ca-doped LaNbO4 (auto) ; Electrophoretic co-deposition (auto) ; Anode functional layer (auto) ; Selectivity analysis (auto) ; Electrochemical characterization (auto)
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