Journal Article PreJuSER-21033

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Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC

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2012
Elsevier New York, NY [u.a.]

International journal of hydrogen energy 37, 8027 - 8032 () [10.1016/j.ijhydene.2011.11.002]

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Abstract: The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H-2. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Keyword(s): J ; Solid oxide fuel cells (auto) ; Ca-doped LaNbO4 (auto) ; Electrophoretic co-deposition (auto) ; Anode functional layer (auto) ; Selectivity analysis (auto) ; Electrochemical characterization (auto)


Note: This work has been funded by the EU within the FP7 project Efficient and robust fuel cell with novel ceramic proton conducting electrolyte (EFFIPRO), grant agreement 227560

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellverfahren (IEK-1)
Research Program(s):
  1. Rationelle Energieumwandlung (P12)
  2. EFFIPRO - Efficient and robust fuel cell with novel ceramic proton conducting electrolyte (227560) (227560)

Appears in the scientific report 2012
Database coverage:
Medline ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2012-11-13, last modified 2024-07-08



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