%0 Journal Article
%A Fielden, J.
%A Quasdorf, K.
%A Cronin, L.
%A Kögerler, P.
%T A Fluorophosphate-Based Inverse Keggin Structure
%J Dalton transactions
%V 41
%N 33
%@ 1477-9226
%C London
%I Soc.
%M PreJuSER-22279
%P 9876-9878
%D 2012
%Z We thank Claire Besson, Arkady Ellern and De-Liang Long for helpful discussions. Work at the Ames Laboratory (initial synthesis and structural characterization) was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358.
%X An unusual PFO(3)(2-)-templated "inverse Keggin" polyanion, [Mo(12)O(46)(PF)(4)](4-), has been isolated from the degradation reaction of an {Mo(132)}-type Keplerate to [PMo(12)O(40)](3-) by [Cu(MeCN)(4)](PF(6)) in acetonitrile. (31)P-NMR studies suggest a structure-directing role for [Cu(MeCN)(4)](+) in the formation of the highly unusual all-inorganic inverse Keggin structure.
%K J (WoSType)
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:22821171
%U <Go to ISI:>//WOS:000307018900012
%R 10.1039/c2dt30501a
%U https://juser.fz-juelich.de/record/22279