Journal Article

PreJuSER-22279

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png A Fluorophosphate-Based Inverse Keggin Structure

Fielden, J. ; Quasdorf, K. ; Cronin, L. ; Kögerler, P.FZJ*

2012
Soc. London

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Please use a persistent id in citations: http://hdl.handle.net/2128/7519  doi:10.1039/C2DT30501A

Abstract: An unusual PFO(3)(2-)-templated "inverse Keggin" polyanion, [Mo(12)O(46)(PF)(4)](4-), has been isolated from the degradation reaction of an {Mo(132)}-type Keplerate to [PMo(12)O(40)](3-) by [Cu(MeCN)(4)](PF(6)) in acetonitrile. (31)P-NMR studies suggest a structure-directing role for [Cu(MeCN)(4)](+) in the formation of the highly unusual all-inorganic inverse Keggin structure.

Keyword(s): J

Note: We thank Claire Besson, Arkady Ellern and De-Liang Long for helpful discussions. Work at the Ames Laboratory (initial synthesis and structural characterization) was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2012

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Database coverage:
; ; Allianz-Lizenz / DFG ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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