TY  - JOUR
AU  - Fielden, J.
AU  - Quasdorf, K.
AU  - Cronin, L.
AU  - Kögerler, P.
TI  - A Fluorophosphate-Based Inverse Keggin Structure
JO  - Dalton transactions
VL  - 41
IS  - 33
SN  - 1477-9226
CY  - London
PB  - Soc.
M1  - PreJuSER-22279
SP  - 9876-9878
PY  - 2012
N1  - We thank Claire Besson, Arkady Ellern and De-Liang Long for helpful discussions. Work at the Ames Laboratory (initial synthesis and structural characterization) was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358.
AB  - An unusual PFO(3)(2-)-templated "inverse Keggin" polyanion, [Mo(12)O(46)(PF)(4)](4-), has been isolated from the degradation reaction of an {Mo(132)}-type Keplerate to [PMo(12)O(40)](3-) by [Cu(MeCN)(4)](PF(6)) in acetonitrile. (31)P-NMR studies suggest a structure-directing role for [Cu(MeCN)(4)](+) in the formation of the highly unusual all-inorganic inverse Keggin structure.
KW  - J (WoSType)
LB  - PUB:(DE-HGF)16
C6  - pmid:22821171
UR  - <Go to ISI:>//WOS:000307018900012
DO  - DOI:10.1039/c2dt30501a
UR  - https://juser.fz-juelich.de/record/22279
ER  -