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@ARTICLE{Fielden:22279,
      author       = {Fielden, J. and Quasdorf, K. and Cronin, L. and Kögerler,
                      P.},
      title        = {{A} {F}luorophosphate-{B}ased {I}nverse {K}eggin
                      {S}tructure},
      journal      = {Dalton transactions},
      volume       = {41},
      number       = {33},
      issn         = {1477-9226},
      address      = {London},
      publisher    = {Soc.},
      reportid     = {PreJuSER-22279},
      pages        = {9876-9878},
      year         = {2012},
      note         = {We thank Claire Besson, Arkady Ellern and De-Liang Long for
                      helpful discussions. Work at the Ames Laboratory (initial
                      synthesis and structural characterization) was supported by
                      the Department of Energy-Basic Energy Sciences under
                      Contract No. DE-AC02-07CH11358.},
      abstract     = {An unusual PFO(3)(2-)-templated "inverse Keggin" polyanion,
                      [Mo(12)O(46)(PF)(4)](4-), has been isolated from the
                      degradation reaction of an {Mo(132)}-type Keplerate to
                      [PMo(12)O(40)](3-) by [Cu(MeCN)(4)](PF(6)) in acetonitrile.
                      (31)P-NMR studies suggest a structure-directing role for
                      [Cu(MeCN)(4)](+) in the formation of the highly unusual
                      all-inorganic inverse Keggin structure.},
      keywords     = {J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien},
      pid          = {G:(DE-Juel1)FUEK412},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:22821171},
      UT           = {WOS:000307018900012},
      doi          = {10.1039/c2dt30501a},
      url          = {https://juser.fz-juelich.de/record/22279},
}