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| 001 | 22279 | ||
| 005 | 20190625111351.0 | ||
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| 024 | 7 | _ | |2 DOI |a 10.1039/C2DT30501A |
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| 084 | _ | _ | |2 WoS |a Chemistry, Inorganic & Nuclear |
| 100 | 1 | _ | |0 P:(DE-HGF)0 |a Fielden, J. |b 0 |
| 245 | _ | _ | |a A Fluorophosphate-Based Inverse Keggin Structure |
| 260 | _ | _ | |a London |b Soc. |c 2012 |
| 300 | _ | _ | |a 9876-9878 |
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| 440 | _ | 0 | |0 15301 |a Dalton Transactions |v 41 |x 1477-9226 |y 9876 - 9878 |
| 500 | _ | _ | |3 POF3_Assignment on 2016-02-29 |
| 500 | _ | _ | |a We thank Claire Besson, Arkady Ellern and De-Liang Long for helpful discussions. Work at the Ames Laboratory (initial synthesis and structural characterization) was supported by the Department of Energy-Basic Energy Sciences under Contract No. DE-AC02-07CH11358. |
| 520 | _ | _ | |a An unusual PFO(3)(2-)-templated "inverse Keggin" polyanion, [Mo(12)O(46)(PF)(4)](4-), has been isolated from the degradation reaction of an {Mo(132)}-type Keplerate to [PMo(12)O(40)](3-) by [Cu(MeCN)(4)](PF(6)) in acetonitrile. (31)P-NMR studies suggest a structure-directing role for [Cu(MeCN)(4)](+) in the formation of the highly unusual all-inorganic inverse Keggin structure. |
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