%0 Journal Article
%A Zhu, G.
%A Geletii, Y.V.
%A Kögerler, P.
%A Schilder, H.
%A Song, J.
%A Lense, S.
%A Zhao, C.
%A Hardcastle, K.I.
%A Musaev, D.G.
%A Hill, C.L.
%T Water Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11
%J Dalton transactions
%V 41
%@ 1477-9226
%C London
%I Soc.
%M PreJuSER-22364
%P 2084 - 2090
%D 2012
%Z The present research is supported by grant DE-FG02-03ER15461 from the U.S. Department of Energy. The authors gratefully acknowledge NSF MRI-R2 grant (CHE-0958205) and the use of the resources of the Cherry Emerson Center for Scientific Computation.
%X A new polyoxometalate of earth adundant elements [{Co(4)(μ-OH)(H(2)O)(3)}(Si(2)W(19)O(70))](11-) has been synthesized, characterized and shown to be a water oxidation catalyst. The initial catalytic complex is unstable and slowly undergoes hydrolysis. The hydrolysis products have been isolated and characterized, and their catalytic water oxidation activity is assessed.
%K J (WoSType)
%F PUB:(DE-HGF)16
%9 Journal Article
%$ pmid:22186630
%U <Go to ISI:>//WOS:000299505100020
%R 10.1039/c1dt11211b
%U https://juser.fz-juelich.de/record/22364